Dr. Christian Frech Nabold
Dr. Christian Frech Nabold
ZHAW
School of Life Sciences and Facility Management
Fachgruppe Grundlagenchemie
Einsiedlerstrasse 31
8820 Wädenswil
Membership of networks
Publications
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Oberholzer, Miriam; Frech Nabold, Christian M.,
2014.
Journal of Visualized Experiments.
Available from: https://doi.org/10.3791/51444
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Oberholzer, Miriam; Frech Nabold, Christian M.,
2013.
Green Chemistry.
2013(6), pp. 1678-1686.
Available from: https://doi.org/10.1039/c3gc40493e
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Gerber, Roman; Frech, Christian M.,
2012.
Chemistry - A European Journal.
18(29), pp. 8901-8905.
Available from: https://doi.org/10.1002/chem.201200388
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Gerber, Roman; Oberholzer, Miriam; Frech, Christian M.,
2012.
Chemistry - A European Journal.
18(10), pp. 2978-2986.
Available from: https://doi.org/10.1002/chem.201102936
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Oberholzer, Miriam; Gerber, Roman; Frech, Christian M.,
2012.
Advanced Synthesis & Catalysis.
354(4), pp. 627-641.
Available from: https://doi.org/10.1002/adsc.201100646
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Fetz, Marco; Gerber, Roman; Blacque, Olivier; Frech, Christian M.,
2011.
Chemistry - A European Journal.
17(17), pp. 4732-4736.
Available from: https://doi.org/10.1002/chem.201003543
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Bolliger, Jeanne L.; Oberholzer, Miriam; Frech, Christian M.,
2011.
Access to 2-aminopyridines : compounds of great biological and chemical significance.
Advanced Synthesis & Catalysis.
353(6), pp. 945-954.
Available from: https://doi.org/10.1002/adsc.201000942
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Gerber, Roman; Blacque, Olivier; Frech Nabold, Christian M.,
2011.
Dalton Transactions.
40(35), pp. 8996-9003.
Available from: https://doi.org/10.1039/c1dt10398a
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Gerber, Roman; Frech, Christian M.,
2011.
Chemistry - A European Journal.
17(42), pp. 11893-11904.
Available from: https://doi.org/10.1002/chem.201101037
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Agrawal, Divya; Schröder, Detlef; Frech, Christian M.,
2011.
Organometallics.
30(13), pp. 3579-3587.
Available from: https://doi.org/10.1021/om200274z
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Bolliger, Jeanne L.; Frech, Christian M.,
2010.
Chemistry - A European Journal.
16(36), pp. 11072-11081.
Available from: https://doi.org/10.1002/chem.201001201
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Bolliger, Jeanne L.; Frech, Christian M.,
2010.
Chemistry - A European Journal.
16(13), pp. 4075-4081.
Available from: https://doi.org/10.1002/chem.200903309
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Jiang, Yanfeng; Blacque, Olivier; Fox, Thomas; Frech, Christian M.; Berke, Heinz,
2010.
Chemistry - A European Journal.
16(7), pp. 2240-2249.
Available from: https://doi.org/10.1002/chem.200902600
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Blacque, Olivier; Frech, Christian M.,
2010.
Pincer-type Heck catalysts and mechanisms based on PdIV intermediates : a computational study.
Chemistry - A European Journal.
16(5), pp. 1521-1531.
Available from: https://doi.org/10.1002/chem.200902091
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Gerber, Roman; Fox, Thomas; Frech, Christian M.,
2010.
Chemistry - A European Journal.
16(23), pp. 6771-6775.
Available from: https://doi.org/10.1002/chem.201000247
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Frech, Christian M.,
2010.
ChemCatChem.
2(11), pp. 1387-1389.
Available from: https://doi.org/10.1002/cctc.201000222
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Bolliger, Jeanne L.; Frech, Christian M.,
2010.
Advanced Synthesis & Catalysis.
352(6), pp. 1075-1080.
Available from: https://doi.org/10.1002/adsc.200900848
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Maccaroni, Elisabetta; Dong, Hailin; Blacque, Olivier; Schmalle, Helmut W.; Frech, Christian M.; Berke, Heinz,
2010.
Water soluble phosphine rhenium complexes.
Journal of Organometallic Chemistry.
695(4), pp. 487-494.
Available from: https://doi.org/10.1016/j.jorganchem.2009.11.031
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Bolliger, Jeanne L.; Frech, Christian M.,
2009.
Aminophosphine palladium pincer complexes for Suzuki and Heck reactions.
Chimia.
63(1-2), pp. 23-28.
Available from: https://doi.org/10.2533/chimia.2009.23
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Jiang, Yanfeng; Blacque, Olivier; Fox, Thomas; Frech, Christian M.; Berke, Heinz,
2009.
From alkynes to carbenes mediated by [Re(Br)(H)(NO)(PR3)2] (R = Cy,iPr) complexes.
Organometallics.
28(16), pp. 4670-4680.
Available from: https://doi.org/10.1021/om900459x
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Bolliger, Jeanne L.; Frech, Christian M.,
2009.
Advanced Synthesis & Catalysis.
351(6), pp. 891-902.
Available from: https://doi.org/10.1002/adsc.200900112
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Jiang, Yanfeng; Blacque, Olivier; Fox, Thomas; Frech, Christian M.; Berke, Heinz,
2009.
Highly selective dehydrogenative silylation of alkenes catalyzed by rhenium complexes.
Chemistry - A European Journal.
15(9), pp. 2121-2128.
Available from: https://doi.org/10.1002/chem.200802019
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Frech, C. M.; Llamazares, A.; Blacque, O.; Schmalle, H. W.; Berke, H.,
2009.
Organometallics.
28(18), pp. 5333-5340.
Available from: https://doi.org/10.1021/om9003412
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Gerber, Roman; Blacque, Olivier; Frech, Christian M.,
2009.
ChemCatChem.
1(3), pp. 393-400.
Available from: https://doi.org/10.1002/cctc.200900169
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Bolliger, Jeanne L.; Frech, Christian M.,
2009.
Tetrahedron.
65(6), pp. 1180-1187.
Available from: https://doi.org/10.1016/j.tet.2008.11.072
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Frech, Christian M.; Shimon, Linda J. W.; Milstein, David,
2009.
Unsaturated Rh(I) and Rh(III) naphthyl-based PCP complexes : major steric effect on reactivity.
Organometallics.
28(6), pp. 1900-1908.
Available from: https://doi.org/10.1021/om801147w
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Frech, Christian M.; Leitus, Gregory; Milstein, David,
2008.
Processes involved in the reduction of a cyclometalated palladium(II) complex.
Organometallics.
27(5), pp. 894-899.
Available from: https://doi.org/10.1021/om7008815
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Bolliger, Jeanne L.; Blacque, Olivier; Frech, Christian M.,
2008.
Chemistry - A European Journal.
14(26), pp. 7969-7977.
Available from: https://doi.org/10.1002/chem.200800441
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Bolliger, Jeanne L.; Blacque, Olivier; Frech, Christian M.,
2007.
Bis[2,6-bis(dipiperidin-1-ylphosphanyloxy)phenyl]bromidopalladium(II).
Acta Crystallographica.
E63(m3086).
Available from: https://doi.org/10.1107/S1600536807059405
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Frech, Christian M.; Shimon, Linda J. W.; Milstein, David,
2007.
Chemistry - A European Journal.
13(26), pp. 7501-7509.
Available from: https://doi.org/10.1002/chem.200700320
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Bolliger, Jeanne L.; Blacque, Olivier; Frech, Christian M.,
2007.
Angewandte Chemie: International Edition.
46(34), pp. 6514-6517.
Available from: https://doi.org/10.1002/anie.200701804
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Frech Nabold, Christian M.; Blacque, Olivier; Schmalle, Helmut W.; Berke, Heinz; Adlhart, Christian; Chen, Peter,
2006.
Chemistry - A European Journal.
12(12), pp. 3325-3338.
Available from: https://doi.org/10.1002/chem.200501025
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Frech, Christian M.; Milstein, David,
2006.
Journal of the American Chemical Society.
128(38), pp. 12434-12435.
Available from: https://doi.org/10.1021/ja064945d
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Frech, C. M.; Blacque, O.; Schmalle, H. W.; Berke, H.,
2006.
Ligand controlled dioxygen oxidation of rhenium nitrosyl complexes.
Dalton Transactions.
35(38), pp. 4590-4598.
Available from: https://doi.org/10.1039/b604858g
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Frech, Christian M.; Shimon, Linda J. W.; Milstein, David,
2006.
Helvetica Chimica Acta.
89(8), pp. 1730-1739.
Available from: https://doi.org/10.1002/hlca.200690170
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Frech, C. M.; Blacque, O.; Schmalle, H. W.; Berke, H.,
2006.
Chemistry - A European Journal.
12(20), pp. 5199-5209.
Available from: https://doi.org/10.1002/chem.200600286
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Frech, Christian M.; Ben-David, Yehoshoa; Weiner, Lev; Milstein, David,
2006.
Metal-controlled reactivity of a pincer-type, σ-coordinated naphthyl radical anion.
Journal of the American Chemical Society.
128(22), pp. 7128-7129.
Available from: https://doi.org/10.1021/ja0615066
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Frech, Christian M.; Shimon, Linda J. W.; Milstein, David,
2005.
Angewandte Chemie: International Edition.
44(11), pp. 1709-1711.
Available from: https://doi.org/10.1002/anie.200462386
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Frech, C. M.; Llamazares, A.; Alfonso, M.; Schmalle, H. W.; Berke, H.,
2004.
Reactions of [Re(NO)2(PR3)2][BArF4] complexes with phenylacetylene.
Russian Chemical Bulletin.
53(5), pp. 1116-1120.
Available from: https://doi.org/10.1023/B:RUCB.0000041309.19570.1d
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Frech, Christian Manfred; Blacque, Olivier; Berke, Heinz,
2006.
Dinitrosyl rhenium complexes for ring-opening metathesis polymerization (ROMP) [paper].
In:
International Symposium on Fine Chemistry and Functional Polymers (FCFP-XV) and the 1st International Symposium on Novel Materials and Synthesis (NMS-I), Shanghai, China, 17-20 October 2005.
Berlin:
De Gruyter.
pp. 1877-1887.
Available from: https://doi.org/10.1351/pac200678101877
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Berke, Heinz; Frech Nabold, Christian M.; Blacque, Olivier; Adlhart, Christian; Chen, Peter,
2005.
Journal of Fudan University.
44(4), pp. 625.
Publications before appointment at the ZHAW
2012
41. Alkyne hydrothiolation catalyzed by a dichloro-bis(aminophosphine) complex of palladium: Selective formation of cis-configured vinyl thioethers R. Gerber, C. M. Frech* Chem. Eur. J. 2012, 18, 8901.
40. Cyanation of aryl bromides with K4[Fe(CN)6] catalyzed by dichloro{bis[1-(dicyclohexyl-phosphanyl)-piperidine]}palladium – a molecular source of nanoparticles. Reactions involved in catalyst deacti-vation processes R. Gerber, C. M. Frech* Chem. Eur. J. 2012, 18, 2978.
39. Mizoroki-Heck reactions catalyzed by dichloro{bis[1-(dicyclohexylphosphanyl)piperi-dine]}palladi-um. Palladium nanoparticle formation promoted by (water induced) ligand degradation M. Oberholzer, R. Gerber, C. M. Frech* Adv. Synth. Catal. 2012, 354, 627.
2011
38. Negishi cross-coupling reactions catalyzed by an aminophosphine based nickel system. A reliable and general applicable reaction protocol for the high-yielding synthesis of biaryls R. Gerber,C. M. Frech* Chem. Eur. J. 2011, 17, 11893.
37. Observation of binuclear palladium clusters upon ESI-MS monitoring of the Suzuki-Miyaura cross-coupling catalyzed by a dichloro-bis(aminophosphine) complex of palladium D. Agrawal, D. Schröder,* C. M. Frech Organometallics 2011, 30, 3579.
36. Negishi cross-coupling reaction catalyzed by an aliphatic, phosphine based pincer complex of palladium. Biaryl formation via cationic pincer-type Pd(IV) intermediates R. Gerber, C. M. Frech* Dalton Trans. 2011, 40, 8996. Invited contribution for a themed issue.
35. Hydrolysis of ammonia-borane catalyzed by aminophosphine-stabilized precursors of rhodium nanoparticles. Ligand-effects and solvent-controlled product formation M. Fetz, R. Gerber, O. Blacque, C. M. Frech* Chem. Eur. J. 2011, 17, 4732.
34. Access to 2-aminopyridines – compounds of great biological and chemical significance J. L. Bolliger, M. Oberholzer, C. M. Frech* Adv. Synth. & Catal. 2011, 353, 945.
2010
33. Reactions within molecular single crystals of inorganic and organometallic compounds. Recent advances and implications for catalysis (highlight article), C. M. Frech* ChemCatChem. 2010, 2, 1387.
32. Dichloro{bis[1-(dicyclohexylphosphanyl)piperidine]}palladium - A Highly Effective and Extremely Versatile Palladium-based Negishi Catalyst, that Efficiently and Reliably Operates at Low Catalyst Loadings J. L. Bolliger, C. M. Frech* Chem. Eur. J., 2010, 16, 11072.
31. PCsp3P and PCsp2P Palladium(II) Hydride Pincer Complexes. Small Structural Difference – Large Effect on Reactivity R. Gerber, T. Fox, C. M. Frech* Chem. Eur. J. 2010, 16, 6771.
30. The 1,3-Diaminobenzene-Derived Aminophosphine Palladium Pincer Complex {C6H3[NHP(piperidin-yl)2]2Pd(Cl)} - A highly active pincer-type Suzuki-Miyaura catalyst with excellent functional group tolerance J. L. Bolliger, C. M. Frech* Adv. Synth. & Catal. 2010, 352, 1075.
29. Facile Synthetic Access to Rhenium(II) Complexes: Activation of Carbon–Bromine Bonds by Single-Electron Transfer Y. Jiang, O. Blacque, T. Fox, C. M. Frech, H. Berke* Chem. Eur. J. 2010, 16, 2240.
28. Dichloro-Bis(aminophosphine) Complexes of Palladium - Highly Convenient, Reliable and Extremely Active Suzuki Catalysts with outstanding functional group tolerance J. L. Bolliger, C. M. Frech* Chem. Eur. J. 2010, 16, 4075.
27. Pincer-type Heck Catalysts and Mechanisms Based on PdIV Intermediates – A Computational Study; O. Blacque, C. M. Frech* Chem. Eur. J. 2010, 16, 1521.
2009
26. The Mizoroki-Heck Reaction (book review), C. M. Frech* Angew. Chem. Int. Ed. 2009, 48, 6947.
25. Development of Rhenium Catalysts for Amine Borane Dehydrocoupling and Transfer Hydrogenation of Olefins Y. Jiang, O. Blacque, T. Fox, C. M. Frech, H. Berke*, Organometallics 2009, 28, 5493.
24. From Alkynes to Carbenes Mediated by [Re(Br)(H)(NO)(PR3)2] R = Cy, iPr) Complexes Y. Jiang, O. Blacque, T. Fox, C. M. Frech, H. Berke* Organometallics 2009, 28, 4670.
23. Reactivity of cationic dinitrosyl bisphoshine rhenium complexes toward acetylene. Base-controlled product formation C. M. Frech, A. Llamazares, H. W. Schmalle, H. Berke*, Organometallics, 2009, 28, 5333.
21. Suzuki Cross-Coupling Reactions Catalyzed by an Aliphatic Phosphine Based Pincer Complex of Palladium. Evidence for a Molecular Mechanism R. Gerber, O. Blacque, C. M. Frech* ChemCatChem, 2009, 1, 393.
20. Highly selective dehydrogenative silylation of alkenes catalyzed by rhenium complexes Y. Jiang, O. Blacque, T. Fox, C. M. Frech, H. Berke* Chem. Eur. J. 2009, 15, 2121.
19. Highly convenient, clean, fast, and reliable Sonogashira coupling reactions promoted by aminophosphine-based pincer complexes of palladium performed under additive- and amine-free reaction conditions J. L. Bolliger, C. M. Frech* Adv. Synth. & Catal. 2009, 351, 891.
18. Aminophosphine palladium pincer complexes for Suzuki and Heck reactions J. L. Bolliger, C. M. Frech* Chimia 2009, 63, 23.
17. Unsaturated Rh(I) and Rh(III) Naphthyl-Based PCP Complexes. Major Steric Effect on Reactivity C. M. Frech,* L. J. W. Shimon, D. Milstein Organometallics 2009, 28, 1900.
16. Transition metal-free amination of aryl halides-A simple and reliable method for the efficient and high-yielding synthesis of N-arylated amines J. L. Bolliger, C. M. Frech* Tetrahedron 2009, 65, 1180.
2008
15. Rationally designed pincer-type Heck catalysts bearing aminophosphine substituents: PdIV intermediates and palladium nanoparticles J. L. Bolliger, O. Blacque, C. M. Frech* Chem. Eur. J. 2008, 14, 7969.
14. Processes Involved in the Reduction of a Cyclometalated Palladium(II) Complex C. M. Frech,* G. Leitus, D. Milstein Organometallics 2008, 27, 894.
2007
13. Bis[2,6-bis(dipiperidin-1-ylphosphanyloxy)phenyl-]bromidopalladium(II) J. L. Bolliger, O. Blacque, C. M. Frech* Acta Cryst., Sec. E: Structure Reports Online 2007, E63, m3086, m3086/1-m3086/10.
12. Methylene transfer from SnMe groups mediated by a rhodium(I) pincer complex: Sn-C, C-C, and C-H bond activation C. M. Frech,* L. J. W. Shimon, D. Milstein* Chem. Eur. J. 2007, 13, 7501.
11. Short, facile, and high-yielding synthesis of extremely efficient pincer-type Suzuki catalysts bearing aminophosphine substituents J. L. Bolliger, O. Blacque, C. M. Frech* Angew. Chem., Int. Ed.2007, 46, 6514.
2006
10. Direct Observation of Reductive Elimination of Methyl Iodide from a Rhodium(III) Pincer Complex. The Importance of Sterics C. M. Frech, D. Milstein,* J. Am. Chem. Soc.2006, 128,12434.
9. Dinitrosyl Rhenium Complexes for Ring Opening Olefin Metathesis (ROMP) Frech, C. M., O. Blacque, H. Berke* Pure and Appl. Chem. 2006, 78, 1877.
8. Ligand Controlled Dioxygen Oxidation of Rhenium Nitrosyl Complexes C. M. Frech, A. Llamazares, O. Blacque, H. W. Schmalle, H. Berke,* Dalton Trans. 2006, 38, 4590.
7. Ligand Controlled Formation of a Low Valent Pincer Rhodium(I) Dioxygen Adduct Bearing a Very Short O-O Bond C. M. Frech, L. W. Shimon, D. Milstein,* Helv. Chim. Acta, 2006, 89, 1730.
6. Metal controlled reactivity of a pincer-type, σ-coordinated naphthyl radical anion C. M. Frech, Y. Ben-David, L. Weiner, D. Milstein,* J. Am. Chem. Soc. 2006, 128, 7128.
5. Metal Nitrosyl Reactivity: Acetonitrile Promoted Insertion of an Alkylidene into a Nitrosyl Ligand with Fission of the NO Bond; C. M. Frech, O. Blacque, H. W. Schmalle, H. Berke,* Chem. Eur. J., 2006, 12, 5199. This article is highlighted (cover picture).
4. Unprecedented ROMP Activity of Low-valent Rhenium Nitrosyl Complexes. A Mechanistic Evaluation of an Electrophilic Olefin Metathesis System C. M. Frech, O. Blacque, H. W. Schmalle, H. Berke,* Ch. Adlhart, P. Chen, Chem. Eur. J., 2006, 12, 3325.
2004 and 2005
3. New Catalysts for ROMP H. Berke,* C. M. Frech, ; A. Llamazares, O. Blacque, H. W. Schmalle, C. Adlhart, P. Chen, Fudan Xuebao, Ziran Kexueban 2005, 44, 625.
2. Redox-Induced Collapse and Regeneration of a Pincer-Type Complex Framework. A Nonplanar Coordination Mode of Palladium(II) C. M. Frech, L. J. W. Shimon, D. Milstein,* Angew. Chem. Int. Ed. 2005, 44, 2.
1. Reactions of [Re(NO)2(PR3)2][BArF4] complexes with phenylacetylene C. M. Frech, A. Llamazares, M. Alfonso, H. W. Schmalle, H. Berke* Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya) 2004, 53, 1116.