Dr. Christian Frech Nabold

Publications

Articles in scientific journal, peer-reviewed

• Oberholzer, M., & Frech Nabold, C. M. (2014). Mizoroki-Heck cross-coupling reactions catalyzed by dichloro{bis[1,1′,1″-(phosphinetriyl)tripiperidine]}palladium under mild reaction conditions. Journal of Visualized Experiments. https://doi.org/10.3791/51444
• Oberholzer, M., & Frech Nabold, C. M. (2013). Mizoroki–Heck reactions catalyzed by palladium dichloro-bis(aminophosphine) complexes under mild reaction conditions : the importance of ligand composition on the catalytic activity. Green Chemistry, 2013(6), 1678–1686. https://doi.org/10.1039/c3gc40493e
• Oberholzer, M., Gerber, R., & Frech, C. M. (2012). Mizoroki-Heck reactions catalyzed by dichloro{bis[1-(dicyclohexylphosphanyl)piperidine]}palladium : palladium nanoparticle formation promoted by (water-Induced) ligand degradation. Advanced Synthesis & Catalysis, 354(4), 627–641. https://doi.org/10.1002/adsc.201100646
• Gerber, R., Oberholzer, M., & Frech, C. M. (2012). Cyanation of aryl bromides with K4[Fe(CN)6] catalyzed by Dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium, a molecular source of nanoparticles, and the reactions involved in the catalyst-deactivation processes. Chemistry - A European Journal, 18(10), 2978–2986. https://doi.org/10.1002/chem.201102936
• Gerber, R., & Frech, C. M. (2012). Alkyne hydrothiolation catalyzed by a dichlorobis(aminophosphine) complex of palladium : selective formation of cis-configured vinyl thioethers. Chemistry - A European Journal, 18(29), 8901–8905. https://doi.org/10.1002/chem.201200388
• Gerber, R., Blacque, O., & Frech Nabold, C. M. (2011). Negishi cross-coupling reaction catalyzed by an aliphatic, phosphine based pincer complex of palladium biaryl formation via cationic pincer-type PdIV intermediates. Dalton Transactions, 40(35), 8996–9003. https://doi.org/10.1039/c1dt10398a
• Agrawal, D., Schröder, D., & Frech, C. M. (2011). Observation of binuclear palladium clusters upon ESI-MS monitoring of the Suzuki–Miyaura cross-coupling catalyzed by a dichloro-bis(aminophosphine) complex of palladium. Organometallics, 30(13), 3579–3587. https://doi.org/10.1021/om200274z
• Gerber, R., & Frech, C. M. (2011). Negishi cross-coupling reactions catalyzed by an aminophosphine-based nickel system : a reliable and general applicable reaction protocol for the high-yielding synthesis of biaryls. Chemistry - A European Journal, 17(42), 11893–11904. https://doi.org/10.1002/chem.201101037
• Bolliger, J. L., Oberholzer, M., & Frech, C. M. (2011). Access to 2-aminopyridines : compounds of great biological and chemical significance. Advanced Synthesis & Catalysis, 353(6), 945–954. https://doi.org/10.1002/adsc.201000942
• Fetz, M., Gerber, R., Blacque, O., & Frech, C. M. (2011). Hydrolysis of ammonia borane catalyzed by aminophosphine-stabilized precursors of rhodium nanoparticles : ligand effects and solvent-controlled product formation. Chemistry - A European Journal, 17(17), 4732–4736. https://doi.org/10.1002/chem.201003543
• Jiang, Y., Blacque, O., Fox, T., Frech, Christian M., & Berke, H. (2010). Facile synthetic access to rhenium(II) complexes : activation of carbon-bromine bonds by single-electron transfer. Chemistry - A European Journal, 16(7), 2240–2249. https://doi.org/10.1002/chem.200902600
• Gerber, R., Fox, T., & Frech, Christian M. (2010). P Csp3 P and P Csp2 P palladium(II) hydride pincer complexes : small structural difference-large effect on reactivity. Chemistry - A European Journal, 16(23), 6771–6775. https://doi.org/10.1002/chem.201000247
• Maccaroni, E., Dong, H., Blacque, O., Schmalle, H. W., Frech, C. M., & Berke, H. (2010). Water soluble phosphine rhenium complexes. Journal of Organometallic Chemistry, 695(4), 487–494. https://doi.org/10.1016/j.jorganchem.2009.11.031
• Blacque, O., & Frech, Christian M. (2010). Pincer-type Heck catalysts and mechanisms based on PdIV intermediates : a computational study. Chemistry - A European Journal, 16(5), 1521–1531. https://doi.org/10.1002/chem.200902091
• Bolliger, J. L., & Frech, Christian M. (2010). The 1,3-diaminobenzene-derived aminophosphine palladium pincer complex {C6H3[NHP(piperidinyl)2]2Pd(Cl)} : a highly active Suzuki-Miyaura catalyst with excellent functional group tolerance. Advanced Synthesis & Catalysis, 352(6), 1075–1080. https://doi.org/10.1002/adsc.200900848
• Bolliger, J. L., & Frech, C. M. (2010). [Pd(Cl)2{P(NC5H10)(C6H11)2}2] - a highly effective and extremely versatile palladium-based Negishi catalyst that efficiently and reliably operates at low catalyst loadings. Chemistry - A European Journal, 16(36), 11072–11081. https://doi.org/10.1002/chem.201001201
• Frech, C. M. (2010). Reactions within molecular single crystals of inorganic and organometallic compounds : recent advances and implications for catalysis. ChemCatChem, 2(11), 1387–1389. https://doi.org/10.1002/cctc.201000222
• Bolliger, J. L., & Frech, Christian M. (2010). Dichloro-bis(aminophosphine) complexes of palladium : highly convenient, reliable and extremely active Suzuki-Miyaura catalysts with excellent functional group tolerance. Chemistry - A European Journal, 16(13), 4075–4081. https://doi.org/10.1002/chem.200903309
• Jiang, Y., Blacque, O., Fox, T., Frech, C. M., & Berke, H. (2009). From alkynes to carbenes mediated by [Re(Br)(H)(NO)(PR3)2] (R = Cy,iPr) complexes. Organometallics, 28(16), 4670–4680. https://doi.org/10.1021/om900459x
• Gerber, R., Blacque, O., & Frech, Christian M. (2009). Suzuki cross-coupling reactions catalyzed by an aliphatic phosphine-based pincer complex of palladium : evidence for a molecular mechanism. ChemCatChem, 1(3), 393–400. https://doi.org/10.1002/cctc.200900169
• Bolliger, J. L., & Frech, C. M. (2009). Transition metal-free amination of aryl halides : a simple and reliable method for the efficient and high-yielding synthesis of N-arylated amines. Tetrahedron, 65(6), 1180–1187. https://doi.org/10.1016/j.tet.2008.11.072
• Bolliger, J. L., & Frech, Christian M. (2009). Highly convenient, clean, fast, and reliable Sonogashira coupling reactions promoted by aminophosphine-based pincer complexes of palladium performed under additive- and amine-free reaction conditions. Advanced Synthesis & Catalysis, 351(6), 891–902. https://doi.org/10.1002/adsc.200900112
• Jiang, Y., Blacque, O., Fox, T., Frech, Christian M., & Berke, H. (2009). Highly selective dehydrogenative silylation of alkenes catalyzed by rhenium complexes. Chemistry - A European Journal, 15(9), 2121–2128. https://doi.org/10.1002/chem.200802019
• Frech, C. M., Shimon, L. J. W., & Milstein, D. (2009). Unsaturated Rh(I) and Rh(III) naphthyl-based PCP complexes : major steric effect on reactivity. Organometallics, 28(6), 1900–1908. https://doi.org/10.1021/om801147w
• Bolliger, J. L., & Frech, C. M. (2009). Aminophosphine palladium pincer complexes for Suzuki and Heck reactions. Chimia, 63(1-2), 23–28. https://doi.org/10.2533/chimia.2009.23
• Frech, C. M., Llamazares, A., Blacque, O., Schmalle, H. W., & Berke, H. (2009). Reactivity of cationic dinitrosyl bisphosphine rhenium complexes toward acetylene : base-controlled product formation. Organometallics, 28(18), 5333–5340. https://doi.org/10.1021/om9003412
• Bolliger, J. L., Blacque, O., & Frech, Christian M. (2008). Rationally designed pincer-type Heck catalysts bearing aminophosphine substituents : PdIV intermediates and palladium nanoparticles. Chemistry - A European Journal, 14(26), 7969–7977. https://doi.org/10.1002/chem.200800441
• Frech, C. M., Leitus, G., & Milstein, D. (2008). Processes involved in the reduction of a cyclometalated palladium(II) complex. Organometallics, 27(5), 894–899. https://doi.org/10.1021/om7008815
• Frech, Christian M., Shimon, Linda J.  W., & Milstein, D. (2007). Methylene transfer from SnMe groups mediated by a rhodium(I) pincer complex: Sn-C, C-C, and C-H bond activation. Chemistry - A European Journal, 13(26), 7501–7509. https://doi.org/10.1002/chem.200700320
• Bolliger, J. L., Blacque, O., & Frech, Christian M. (2007). Short, facile, and high-yielding synthesis of extremely efficient pincer-type Suzuki catalysts bearing aminophosphine substituents. Angewandte Chemie: International Edition, 46(34), 6514–6517. https://doi.org/10.1002/anie.200701804
• Bolliger, J. L., Blacque, O., & Frech, C. M. (2007). Bis[2,6-bis(dipiperidin-1-ylphosphanyloxy)phenyl]bromidopalladium(II). Acta Crystallographica, E63(m3086). https://doi.org/10.1107/S1600536807059405
• Frech, C. M., Blacque, O., Schmalle, H. W., & Berke, H. (2006). Metal nitrosyl reactivity : acetonitrile-promoted insertion of an alkylidene into a nitrosyl ligand with fission of the NO bond. Chemistry - A European Journal, 12(20), 5199–5209. https://doi.org/10.1002/chem.200600286
• Frech, C. M., Blacque, O., Schmalle, H. W., & Berke, H. (2006). Ligand controlled dioxygen oxidation of rhenium nitrosyl complexes. Dalton Transactions, 35(38), 4590–4598. https://doi.org/10.1039/b604858g
• Frech, Christian M., Shimon, Linda J.  W., & Milstein, D. (2006). Ligand-controlled formation of a low-valent pincer rhodium(I)–dioxygen adduct bearing a very short O-O Bond. Helvetica Chimica Acta, 89(8), 1730–1739. https://doi.org/10.1002/hlca.200690170
• Frech, C. M., & Milstein, D. (2006). Direct observation of reductive elimination of methyl iodide from a rhodium(III) pincer complex : the importance of sterics. Journal of the American Chemical Society, 128(38), 12434–12435. https://doi.org/10.1021/ja064945d
• Frech, C. M., Ben-David, Y., Weiner, L., & Milstein, D. (2006). Metal-controlled reactivity of a pincer-type, σ-coordinated naphthyl radical anion. Journal of the American Chemical Society, 128(22), 7128–7129. https://doi.org/10.1021/ja0615066
• Frech Nabold, C. M., Blacque, O., Schmalle, H. W., Berke, H., Adlhart, C., & Chen, P. (2006). Unprecedented ROMP activity of low-valent rhenium-nitrosyl complexes : mechanistic evaluation of an electrophilic olefin metathesis system. Chemistry - A European Journal, 12(12), 3325–3338. https://doi.org/10.1002/chem.200501025
• Frech, C. M., Shimon, L. J. W., & Milstein, D. (2005). Redox-induced collapse and regeneration of a pincer-type complex framework : a nonplanar coordination mode of palladium(II). Angewandte Chemie: International Edition, 44(11), 1709–1711. https://doi.org/10.1002/anie.200462386
• Frech, C. M., Llamazares, A., Alfonso, M., Schmalle, H. W., & Berke, H. (2004). Reactions of [Re(NO)2(PR3)2][BArF4] complexes with phenylacetylene. Russian Chemical Bulletin, 53(5), 1116–1120. https://doi.org/10.1023/B:RUCB.0000041309.19570.1d

Written conference contributions, peer-reviewed

Frech, C. M., Blacque, O., & Berke, H. (2006). Dinitrosyl rhenium complexes for ring-opening metathesis polymerization (ROMP) [Conference paper]. Pure and Applied Chemistry, 78(10), 1877–1887. https://doi.org/10.1351/pac200678101877

Other publications

Berke, H., Frech Nabold, C. M., Blacque, O., Adlhart, C., & Chen, P. (2005). New catalysts for ROMP. Journal of Fudan University, 44(4), 625.

go back